

REVIEW OF U of IL, CHICAGO TESTING
MECHANICAL PROPERTIES AND DURABILITY OF HIGH PERFORMANCE PROTECRETE®
Concrete:
A summary of
the 180-day progress report by the University of Illinois
at Chicago
February, 1999
INTRODUCTION
The University of Illinois at Chicago was looking
for ways to improve the strength, durability and reliability of concrete. The manufacturer
of PROTECRETE was looking for an independent source of impeccable
reputation to confirm the field tests, which had shown that PROTECRETE Mix Water
ConditionerTM improves the strength, durability and reliability of concrete. Which
brings us to this study...
The U of I is now conducting an extensive study to
evaluate the mechanical properties and long-term corrosion-resisting characteristics of
selectable strength high performance concrete (HPC) using PROTECRETE Mix Water
ConditionerTM. Over 40 mix designs were evaluated before the final selection was
narrowed to just three high quality mixes (with one of the three being treated with PROTECRETE
DensifierTM for a fourth type of concrete), and over 850 specimens have been cast.
The preliminary study will run for one year, and subsequent studies will run for another
estimated two to three years.
OBJECTIVES
The U of I recognizes that HPC is
widely used in the civil infrastructure as a construction and maintenance material, but
many aspects of HPC require further studies in order to understand the
effects of various environments and loads. Corrosion is a serious problem for reinforced
concrete, so finding a way to eliminate corrosion is key. The goal is to create concrete
with adequate compressive strength as well as very low porosity and extremely low
permeability. This is possible by using low water-cement ratios, superplasticizers, Mix
Water ConditionerTM, DensifierTM and appropriate aggregates,
cements, and mineral admixtures.
Cost is also a factor, however. HPC
made using finely divided admixtures is not always reliable and can be complex to use. The
U of I reports that Mix Water ConditionerTM and DensifierTM enhance the
durability of concrete at a fraction of the cost of other pozzolanic materials.
Another objective is to evaluate
permeability, which is among the most relevant characteristics of concrete affecting its
durability. Concretes with equal compressive strength may have different permeabilities,
thus providing different levels of resistance to corrosion.
Mix Water ConditionerTM is being studied
because it yields higher quality concrete at a fraction of the cost, quicker and easier
placement which reduces finishing time, less shrinkage and cracking, stronger bond of
concrete to steel and increased compressive strength. DensifierTM requires only a
one-time permanent application that makes concrete virtually impermeable, while
significantly densifying, improving thermal resistance, increasing strength and lowering
creep deformation potential.
RESULTS
The following conclusions
have been drawn at the end of 180 days:
The addition of Mix Water
ConditionerTM increased the slump through increased lubricity, greatly enhancing the
concrete's workability. It also yielded a better surface finish and improved aesthetic
appearance.
There was a significant increase
in strengths and modulus of elasticity for specimens prepared with Mix Water
ConditionerTM.
The splitting tensile strength at
7 and 14 days was 6 percent lower than the control for the Mix Water ConditionerTM specimens, which
were treated with DensifierTM; however, this strength increased by 6 percent at 28 and 90
days, and subsequently increased at 180 days.
The flexural strengths for the
control specimens were the lowest among all four different types of concrete.
The flexural strengths for the Mix
Water ConditionerTM specimens in both normal and severe environments showed a
continuous increase up to 180 days.
The percentage of air voids in the
Mix Water ConditionerTM specimens is the lowest, by about 50 percent compared to the
control. Mix Water ConditionerTM provides greater density and less permeability.
The use of DensifierTM protects the
surface from abrasion, scaling, and deterioration and prevents the penetration of
aggressive materials. DensifierTM also provides a better surface appearance.
ABOUT THE TESTING
THE MIXES
After careful evaluation, the 40
different mix designs initially tested were narrowed to the following three:
U.S. Customary
| |
Mix proportions, pounds per cubic yard |
MWC,
fluid
ounces |
Slump,
inches |
Water/
cement
Ratio |
Cement
|
Fly ash
|
Water
|
Sand
|
Coarse
aggregate |
| Control |
597 |
-- |
322 |
1460 |
1668 |
-- |
3.5 |
.54 |
| MWC |
597 |
-- |
322 |
1460 |
1668 |
60 |
5.5 |
.54 |
MWC w/
fly ash |
509
|
89
|
300
|
1468
|
1678
|
60
|
4.0
|
.50
|
Metric
| |
Mix proportions, kilograms per cubic meter |
MWC,
liters |
Slump
mm |
Water/
cement
Ratio |
Cement
|
Fly ash
|
Water
|
Sand
|
Coarse
aggregate |
| Control |
354 |
-- |
191 |
866 |
990 |
-- |
87.5 |
.54 |
| MWC |
354 |
-- |
191 |
866 |
990 |
2.31 |
137.5 |
.54 |
MWC w/
fly ash |
302
|
53
|
178
|
871
|
996
|
2.31
|
100
|
.50
|
ENVIRONMENTAL CONDITIONS
The specimens were placed in
three environments prior to testing:
NORMAL: Placed in moisture
room with 100% saturation and a constant temperature of 73°F (23°C) within 24 hours from
casting until testing.
SEVERE: Placed in normal
environment (above) within 24 hours from casting for 7 days. Then placed in tank with 15%
by weight sodium chloride solution until testing. Specimens are fully immersed in the 15%
saline solution for 31/2 days. Then the water is removed leaving the specimens to dry for
another 31/2 days. This weekly wetting and drying process will be continuously performed
for one year.
LAB: Placed in room
temperature and moisture until testing.
MECHANICAL PROPERTIES
US CUSTOMARY
|
No. of
Days |
Environmental Conditions |
Normal |
Severe |
Lab |
Control
|
MWC
|
MWC w/
CDS |
MWC w/
fly ash |
Control
|
MWC
|
MWC w/
CDS |
MWC w/
fly ash |
MWC w/
CDS |
| Compressive
strength (psi) |
7 |
4354 |
4833 |
4514 |
4702 |
4354 |
4833 |
4514 |
4702 |
3817 |
14 |
5486 |
5747 |
5283 |
5544 |
5327 |
5617 |
5065 |
5298 |
4427 |
28 |
6183 |
6604 |
6401 |
6372 |
5951 |
6372 |
5907 |
6212 |
5109 |
90 |
7141 |
7286 |
7257 |
7388 |
6851 |
6909 |
6488 |
6923 |
5472 |
180 |
7221 |
7415 |
7290 |
8061 |
6932 |
7301 |
7027 |
7061 |
5409 |
| Splitting
tensile Strength (psi) |
7 |
436 |
442 |
404 |
420 |
436 |
442 |
404 |
420 |
432 |
14 |
470 |
482 |
444 |
490 |
450 |
476 |
476 |
436 |
474 |
28 |
532 |
534 |
548 |
540 |
516 |
546 |
546 |
526 |
480 |
90 |
580 |
626 |
612 |
642 |
542 |
572 |
558 |
572 |
508 |
180 |
610 |
634 |
640 |
691 |
607 |
623 |
555 |
637 |
|
| Flexural
Strength (psi) |
7 |
527 |
533 |
496 |
626 |
508 |
533 |
496 |
626 |
563 |
14 |
650 |
649 |
559 |
763 |
716 |
705 |
775 |
849 |
575 |
28 |
747 |
774 |
604 |
837 |
765 |
775 |
887 |
970 |
617 |
90 |
785 |
829 |
803 |
843 |
866 |
929 |
951 |
1145 |
781 |
180 |
858 |
905 |
884 |
935 |
952 |
1001 |
1049 |
1236 |
794 |
Modulus of
elasticity (ksi) |
28
|
4238
|
4702
|
4470
|
4644
|
3396
|
4107
|
4049
|
4064
|
3353
|
MECHANICAL PROPERTIES
METRIC
| |
No. of
Days |
Environmental Conditions |
Normal |
Severe |
Lab |
Control
|
MWC
|
MWC w/
CDS |
MWC w/
fly ash |
Control
|
MWC
|
MWC w/
CDS |
MWC w/
fly ash |
MWC w/
CDS |
| Compressive
Strength (MPa) |
7 |
30.0 |
33.3 |
31.1 |
32.4 |
30.0 |
33.3 |
31.1 |
32.4 |
26.3 |
14 |
37.8 |
39.6 |
36.4 |
38.2 |
36.7 |
38.7 |
34.9 |
36.5 |
30.5 |
28 |
42.6 |
45.5 |
44.1 |
43.9 |
41.0 |
43.9 |
40.7 |
42.8 |
35.2 |
90 |
49.2 |
50.2 |
500 |
50.9 |
47.2 |
47.6 |
44.7 |
47.7 |
37.7 |
180 |
49.8 |
51.1 |
50.3 |
55.6 |
47.8 |
50.3 |
48.4 |
48.7 |
37.3 |
| Splitting
tensile strength (MPa) |
7 |
3.00 |
3.04 |
2.78 |
2.90 |
3.00 |
3.04 |
2.78 |
2.90 |
2.98 |
14 |
3.24 |
3.32 |
3.06 |
3.38 |
3.10 |
3.28 |
3.28 |
3.00 |
3.26 |
28 |
3.66 |
3.68 |
3.78 |
3.72 |
3.56 |
3.76 |
3.76 |
3.62 |
3.32 |
90 |
4.00 |
4.32 |
4.22 |
4.42 |
3.74 |
3.94 |
3.84 |
3.94 |
3.50 |
180 |
4.20 |
4.37 |
4.41 |
4.76 |
4.19 |
4.29 |
3.83 |
4.39 |
-- |
| Flexural
Strength (MPa) |
7 |
3.63 |
3.67 |
3.42 |
4.31 |
3.50 |
3.67 |
3.42 |
4.31 |
3.88 |
14 |
4.48 |
4.47 |
3.85 |
5.26 |
4.93 |
4.86 |
5.34 |
5.85 |
3.96 |
28 |
5.15 |
5.33 |
4.16 |
4.77 |
5.27 |
5.34 |
6.11 |
6.68 |
4.25 |
90 |
5.41 |
5.71 |
5.53 |
5.81 |
5.97 |
6.40 |
6.55 |
7.89 |
5.38 |
180 |
5.92 |
6.24 |
6.10 |
6.45 |
6.56 |
6.90 |
7.23 |
8.52 |
5.47 |
Modulus of
elasticity (GPa) |
28
|
29.2
|
32.4
|
30.8
|
32.0
|
23.4
|
28.3
|
27.9
|
28.0
|
23.1
|
PERMEABILITY
The Mix Water ConditionerTM mix is five
times less permeable than the control mix at the preliminary stage.
| |
Hydraulic
Conductivity, inches/second (cm/second) |
| Control 13 x
10.9 (5.1 x 10'9) 2.5 x 10.9 (1 x 10'9) |
13 x 10-9 (5.1 x 10-9) |
| Mix
Water ConditionerTM |
2.5 x 10-9 (1 x 10-9) |
CHLORIDE CONTENT
Overall, the specimens with Mix
Water ConditionerTM showed the lowest penetration.
A copy of the full 53-page report
may be obtained by contacting your authorized PROTECRETE distributor:
Concrete & Tile
Technologies, Inc.
6501 Geil Lane
Louisville, Kentucky 40219
800/754-2914 or 502/964-5557
FAX 502/964-9930
E-mail: info@concrete-tile.com
Web: http://www.concrete-tile.com
ACKNOWLEDGEMENTS
The ongoing study at the University of Illinois at
Chicago is being performed by Dr. Mohsen A. Issa, Dr. Mahmoud A. Issa, Dr. Mohamad Faraj,
and Dr. Krishna Reddy of the Department of Civil and Mateirals Engineering. Applied
Concrete Technology, Inc., the manufacturer of PROTECRETE, would
like to gratefully acknowledge their thorough and outstanding effort. Thanks are also due
to graduate students Alfred A. Yousif, Mohammad S. Islam, Mark Bendok, and Cyro Luiz
Ribeiro do Valle.

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